Microscopic Phase Structure of Mo-based Catalyst and Its Catalytic Activity for Soot Oxidation

The MoO3 catalysts supported on nano-scale TiO2 with various loading rates (5%, 10%, 20%, and 40%) were prepared by an impregnation method. The phase structures of nano-scale MoO3/TiO2 catalysts were characterized by Brunner-Emmet-Teller, Fourier Transform Infrared Spectra, X-ray Diffraction, and Scanning Electron Microscope. The oxidation activities of catalysts over diesel soot were performed in a Thermogravimetric Analysis system. The kinetics of the catalytic oxidation process was analyzed based on Starink method. The characterization results showed that the phase structure of MoO3 supported on TiO2 depends heavily on the molybdenum contents, which put great effects on soot oxidation. The orthorhombic crystal system (α-MoO3) appeared on the surface of the catalysts when the MoO3 exceeds 10%. Due to the low melting point and good surface mobility of MoO3, the catalytic activity was increased and the characteristic temperatures were decreased with the increase in MoO3 contents. As a result, the activities of catalysts with different loading rates for soot oxidation can be ranked as: Mo5<Mo10<Mo2

Optimized Heating Rate and Soot-catalyst Ratio for Soot Oxidation over MoO3 Catalyst

MoO3 is now utilized as a promising catalyst due to its high activity and favorable mobility at low temperature. Its spectral data and surface microstructures were characterized by Fourier transform infrared spectra (FT-IR) and Field emission scanning electron microscope (FESEM). Thermo-analysis of the carbon black was performed over nano-MoO3 catalyst in a thermogravimetric analyzer (TGA) at various heating rates and soot-catalyst ratios. Through the analysis of kinetic parameters, we found that the heat transfer effect and diffusion effect can be removed by setting lower heating rates and soot-catalyst ratios. Therefore, a strategy for selecting proper thermogravimetric parameters were established, which can contribute to the better understanding of thermo-analytical process.

Optimized Heating Rate and Soot-catalyst Ratio for Soot Oxidation over MoO3 Catalyst

MoO3 is now utilized as a promising catalyst due to its high activity and favorable mobility at low temperature. Its spectral data and surface microstructures were characterized by Fourier transform infrared spectra (FT-IR) and Field emission scanning electron microscope (FESEM). Thermo-analysis of the carbon black was performed over nano-MoO3 catalyst in a thermogravimetric analyzer (TGA) at various heating rates and soot-catalyst ratios. Through the analysis of kinetic parameters, we found that the heat transfer effect and diffusion effect can be removed by setting lower heating rates and soot-catalyst ratios. Therefore, a strategy for selecting proper thermogravimetric parameters were established, which can contribute to the better understanding of thermo-analytical process. Copyright © 2017 BCREC Group. All rights reserved Received: 4th December 2016; Revised: 13rd June 2017; Accepted: 9th April 2017; Available online: 27th October 2017; Published regularly: December 2017 How to Cite: Mei, C., Mei, D., Yue, S, Chen, Z., Yuan, Y. (2017). Optimized Heating Rate and Soot-catalyst Ratio for Soot Oxidation over MoO3 Catalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 12 (3): 408-414 (doi:10.9767/bcrec.12.3.845.408-41

Phy-chemical Attributes of Nano-scale V2O5/TiO2 Catalyst and Its’ Effect on Soot Oxidation

The V2O5 catalysts which supported on nano-scale TiO2 with variation of vanadium contents (5%, 10%, 20% and 40%) were prepared by an incipient-wetness impregnation method. The phase structures of nano-scale V2O5/TiO2 catalysts with different loading rates were characterized by Scanning electron microscope (SEM), X-Ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectra. The oxidation activities of catalysts over diesel soot were performed in a themogravimetric analysis (TGA) system. The kinetics of the catalytic oxidation process were analyzed based on Flynn-Wall-Ozawa method. The characterization results showed that the phase structure of V2O5 supported on TiO2 depends heavily on the vanadium contents, which will put great effects on the catalytic performances for soot oxidation. At a low vanadium loading rates (V5-V20), active species exist as monomers and polymeric states. At a high loading rate (V40), the crystalline bulk V2O5 covers the surface of TiO2. The formed crystal structure occupied the active sites and led a decreasing in the catalytic effect. By comparing the characteristics temperatures of soot oxidation over V2O5 catalysts, the catalytic activities of catalysts with different loading rates for soot oxidation can be ranked as: V5 < V10 < V40 < V20. Via pyrolysis kinetics analysis, it is revealed that the activation energy of soot oxidation is minimum when the vanadium loading rates is 20%, which is fit well with the TG experimental results. The consistency of pyrolysis kinetics and TG experimental results confirm that the best activity catalyst is V20 in discussed catalysts of this paper, which is nearest to the monolayer dispersion saturated state of V2O5/TiO2 catalyst. Moreover, it convincingly demonstrate the obvious threshold effect in V2O5 catalysts.

Microscopic Phase Structure of Mo-based Catalyst and Its Catalytic Activity for Soot Oxidation

The MoO3 catalysts supported on nano-scale TiO2 with various loading rates (5%, 10%, 20%, and 40%) were prepared by an impregnation method. The phase structures of nano-scale MoO3/TiO2 catalysts were characterized by Brunner-Emmet-Teller, Fourier Transform Infrared Spectra, X-ray Diffraction, and Scanning Electron Microscope. The oxidation activities of catalysts over diesel soot were performed in a Thermogravimetric Analysis system. The kinetics of the catalytic oxidation process was analyzed based on Starink method. The characterization results showed that the phase structure of MoO3 supported on TiO2 depends heavily on the molybdenum contents, which put great effects on soot oxidation. The orthorhombic crystal system (α-MoO3) appeared on the surface of the catalysts when the MoO3 exceeds 10%. Due to the low melting point and good surface mobility of MoO3, the catalytic activity was increased and the characteristic temperatures were decreased with the increase in MoO3 contents. As a result, the activities of catalysts with different loading rates for soot oxidation can be ranked as: Mo

Research Progress of Battery Life Prediction Methods Based on Physical Model

Remaining useful life prediction is of great significance for battery safety and maintenance. The remaining useful life prediction method, based on a physical model, has wide applicability and high prediction accuracy, which is the research hotspot of the next generation battery life prediction method. In this study, the prediction methods of battery life were compared and analyzed, and the prediction methods based on the physical model were summarized. The prediction methods were classified according to their different characteristics including the electrochemical model, equivalent circuit model, and empirical model. By analyzing the emphasis of electrochemical process simplification, different electrochemical models were classified including the P2D model, SP model, and electrochemical fusion model. The equivalent circuit model was divided into the Rint model, Thevenin model, PNGV model, and RC model for the change of electronic components in the model. According to the different mathematical expressions of constructing the empirical model, it can be divided into the exponential model, polynomial model, exponential and polynomial mixed model, and capacity degradation model. Through the collocation of different filtering methods, the different efficiency of the models is described in detail. The research progress of various prediction methods as well as the changes and characteristics of traditional models were compared and analyzed, and the future development of battery life prediction methods was prospected

Effect of Different Hot-Pressing Pressure and Temperature on the Performance of Titanium Mesh-Based MEA for DMFC

The hot-pressing process of the membrane electrode assembly (MEA) is one of the research hotspots in the field of the fuel cell. To obtain suitable titanium mesh-based MEA hot pressing process parameters, titanium mesh was used as electrode substrate material. The anode and cathode of MEA were prepared by the drip-coated method, and the titanium mesh-based MEA was prepared under different hot-pressing pressure and temperature, respectively. The performance of titanium mesh-based MEA was studied by morphological observation, elemental analysis, thickness measurement, single cell test and numerical fitting analysis. The results demonstrated that: with increasing hot-pressing pressure from 0 MPa to 10 MPa, the forming thickness of titanium mesh-based MEA is getting thin gradually, and the peak power density of titanium mesh-based MEA first increased and then gradually decreased; with increasing hot-pressing temperature from 115 &deg;C to 155 &deg;C, the peak power density of titanium mesh-based MEA enhanced at the beginning and then also gradually decreased. Under the premise of a hot-pressing time of 180 s and the optimal operating temperature of DMFC of 60 &deg;C, the appropriate hot-pressing process conditions of titanium mesh-based MEA are a hot-pressing pressure of 5 MPa and a hot-pressing temperature of 135 &deg;C. The results can provide a technological reference for the preparation of titanium mesh MEA for DMFC

A Review of the Power Battery Thermal Management System with Different Cooling, Heating and Coupling System

The battery thermal management system is a key skill that has been widely used in power battery cooling and preheating. It can ensure that the power battery operates safely and stably at a suitable temperature. In this article, we summarize mainly summarizes the current situation for the research on the thermal management system of power battery, comprehensively compares and analyzes four kinds of cooling systems including air cooling, liquid cooling, phase-change materials and heat pipe, two types of heating systems including internal heating and external heating, and the corresponding characteristics of the coupled system in no less than two ways. It is found that liquid cooling system and its heating system, phase-change material cooling system and it is heating system, heat pipe cooling system, coupling cooling system and its heating system have great research prospects, it also provides a certain reference for future research directions

Influence of Different Ambient Temperatures on the Discharge Performance of Square Ternary Lithium-Ion Batteries

Electric vehicles have a promising development prospect. As its core component, lithium-ion power battery plays a crucial role in different application scenarios. Aiming at the availability and safety of square ternary lithium batteries at different ambient temperatures and different current rates, charge-discharge cycle experiments are carried out to study the voltage, temperature and capacity changes of lithium batteries. The voltage plateau characteristics of lithium batteries under different working conditions are explored. The results show that when discharging at current rates of 0.1C, 0.25C, 0.5C, 0.75C, and 1C under the ambient temperature of &minus;5 &deg;C, 10 &deg;C, 25 &deg;C, and 40 &deg;C, the terminal voltage of the battery changes smoothly during the voltage plateau period, the rise of the surface temperature has not reached the peak value, and the discharge capacity accounts for about 50%. The battery has better working performance. While at the ambient temperature of &minus;20 &deg;C, the discharge capacity accounts for the highest proportion in the stage from the open-circuit voltage to the initial voltage of the plateau period. The research results can provide a reference for the modeling and control strategy design of lithium-ion power batteries in the energy storage system of electric vehicles